skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Search for: All records

Creators/Authors contains: "Wick, Collin D"

Note: When clicking on a Digital Object Identifier (DOI) number, you will be taken to an external site maintained by the publisher. Some full text articles may not yet be available without a charge during the embargo (administrative interval).
What is a DOI Number?

Some links on this page may take you to non-federal websites. Their policies may differ from this site.

  1. Free, publicly-accessible full text available February 1, 2026
  2. Abstract We analyzed the effects of crosslinking fraction and number of functional sites per hardener molecule on the stress recovery and topology of thermoset shape memory polymers (TSMPs) via coarse-grained molecular dynamics simulations. After systematically varying the quality of the crosslinked network by manipulating the number of unique epoxies reacted with each hardener, we found that two fingerprints correlate well with stress recovery of TSMPs. These fingerprints are the fraction of epoxy molecules connected to two distinct hardener molecules, and the fraction of molecules that are part of the largest or main network in the system. Their product can be used as a topological score ( S topo ) to quantify the topological feature of the network. When analyzing stress recovery as a function of S topo , we found a strong correlation between S topo and recovery stress. Moreover, we observed that while a higher crosslinking fraction did frequently lead to a higher stress recovery, many exceptions existed. High functionality hardeners tend to exhibit higher stress recovery at similar S topo , especially at high (>0.65) S topo . These results suggest that increasing the number of functional sites per hardener molecule combined with improving the topology of the network with a method such as semi batch monomer addition can lead to an improvement in the stress recovery of TSMPs. 
    more » « less
  3. null (Ed.)